there are many ways to do it, but I will show just two of them.
The first way is doing the following:
Using the wp_print_styles tag:
add_action('wp_print_styles', 'add_my_stylesheet');
function add_my_stylesheet() {
$myStyleUrl = WP_PLUGIN_URL . '/myPlugin/';
$myStyleFile = WP_PLUGIN_DIR . 'style.css';
if ( file_exists($myStyleFile) ) {
wp_register_style('myStyleSheets', $myStyleUrl);
wp_enqueue_style( 'myStyleSheets');
}
}
The second way is printing it on the header file.
add_action('wp_head', 'business_directory_css');
function business_directory_css(){
global $bizdir_relative;
echo '<link type="text/css" rel="stylesheet" href="'.get_option("siteurl") . '/wp-content/plugins/myplugin/mycssstyle.css'" />' . "\n";
}
I thing the second one is easier.